- Physical Chemistry I
Spring 2013 Unique 52575
Lecture Summary, 14 January 2013
to Thermodynamics: We have spent most of our first day defining the subject of thermodynamics, and discussion the
most important principles of the field. Thermodynamics is the
science that studies the effect on matter from the transfer of
energy through heat or work. Thermodynamics does not require
any assumptions or understanding of the physical nature of the
underlying system. Because of that, this science can be used
to understand the properties of systems in which the physical
composition is overwhelmingly complicated or completely
state: a system containing a set of defined properties that do not depend on history.
property: a variable that can be measured, implied, or manipulated.
path: the process by which a state moves from an initial to a final set of properties. Paths do depend on history and circumstances. Much of our study of thermodynamics will be spent trying to define paths in an intelligent way.
equilibrium: the point at which all forces are equal; the state at which the system is at a minimum potential energy.
reversibility: a path that is in instantaneous equilibrium at every point. There are very few macroscopic examples of reversible paths (frictionless pendulum). However, this is an incredibly important concept of microscopic paths.